Electric-field induced phase transitions in capillary electrophoretic systems

dc.authoridErim, Fatma Bedia/0000-0001-9406-6681
dc.authoridBerker, A/0000-0002-5172-2172
dc.authoridKaygusuz, Hakan/0000-0001-9336-1902
dc.authorwosidErim, Fatma Bedia/A-7629-2016
dc.contributor.authorKaygusuz, Hakan
dc.contributor.authorErim, F. Bedia
dc.contributor.authorBerker, A. Nihat
dc.date.accessioned2023-10-19T15:11:32Z
dc.date.available2023-10-19T15:11:32Z
dc.date.issued2021
dc.department-temp[Kaygusuz, Hakan] Altinbas Univ, Fac Engn & Nat Sci, Dept Basic Sci, TR-34218 Istanbul, Turkey; [Kaygusuz, Hakan] Sabanci Univ, SUNUM Nanotechnol Res Ctr, TR-34956 Istanbul, Turkey; [Erim, F. Bedia] Istanbul Tech Univ, Fac Sci & Letters, Dept Chem, TR-34469 Istanbul, Turkey; [Berker, A. Nihat] Kadir Has Univ, Fac Engn & Nat Sci, TR-34083 Istanbul, Turkey; [Berker, A. Nihat] MIT, Dept Phys, Cambridge, MA 02139 USAen_US
dc.description.abstractThe movement of particles in a capillary electrophoretic system under electroosmotic flow was modeled using Monte Carlo simulation with the Metropolis algorithm. Two different cases with repulsive and attractive interactions between molecules were taken into consideration. Simulation was done using a spin-like system, where the interactions between the nearest and second closest neighbors were considered in two separate steps of the modeling study. A total of 20 different cases with different rates of interactions for both repulsive and attractive interactions were modeled. The movement of the particles through the capillary is defined as current. At a low interaction level between molecules, a regular electroosmotic flow is obtained; on the other hand, with increasing interactions between molecules, the current shows a phase transition behavior. The results also show that a modular electroosmotic flow can be obtained for separations by tuning the ratio between molecular interactions and electric field strength.en_US
dc.description.sponsorshipAcademy of Sciences of Turkey (TUBA)en_US
dc.description.sponsorshipA. Nihat Berker gratefully acknowledges the support from the Academy of Sciences of Turkey (TUBA).en_US
dc.identifier.citation3
dc.identifier.doi10.1063/5.0065824en_US
dc.identifier.issn1070-6631
dc.identifier.issn1089-7666
dc.identifier.issue10en_US
dc.identifier.scopus2-s2.0-85118196738en_US
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1063/5.0065824
dc.identifier.urihttps://hdl.handle.net/20.500.12469/5065
dc.identifier.volume33en_US
dc.identifier.wosWOS:000721611800003en_US
dc.identifier.wosqualityQ1
dc.khas20231019-WoSen_US
dc.language.isoenen_US
dc.publisherAip Publishingen_US
dc.relation.ispartofPhysics of Fluidsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectMonte-Carlo-SimulationEn_Us
dc.subjectStochastic SimulationEn_Us
dc.subjectPerformanceEn_Us
dc.subjectDimensionsEn_Us
dc.subjectSeparationEn_Us
dc.subjectModelEn_Us
dc.subjectMonte-Carlo-Simulation
dc.subjectStochastic Simulation
dc.subjectPerformance
dc.subjectDimensions
dc.subjectSeparation
dc.subjectModel
dc.titleElectric-field induced phase transitions in capillary electrophoretic systemsen_US
dc.typeArticleen_US
dspace.entity.typePublication

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