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Citation Count: 4
Atomic force microscopy and spectroscopy studies of annealed Ce/Ti/Zr mixed oxide thin films prepared by sol-gel process
(Elsevier Science Bv, 2006) Ghodsi, Farhad E.; Tepehan, Fatma Zehra; Tepehan, Galip Gültekin
Mixed Ce/Ti/Zr oxide thin films with a molar ratio of 0.5:0.25:0.25 were prepared using the sol-gel process and deposited on glass substrates by the dip coating technique. The effect of heat treatment temperature on surface morphology of the films was examined by atomic force microscopy AFM. The optical transmittance and reflectance of the films were measured over the spectral range from 350 to 1000 nm. The refractive index and extinction coefficient and thickness of the films were determined as a function of the heat treatment temperature. The refractive index increased from 1.51 to 2.02 at lambda = 600 nm and the extinction coefficient values increased from 0.006 to 0.094 while the thickness of the films decreased from 81 nm to 45 nm when annealing temperature increased from 100 degrees C to 500 degrees C. The results show that the optical properties and surface morphology of the mixed Cc/Ti/Zr oxide thin films were affected by annealing temperature. (c) 2006 Elsevier B.V. All rights reserved.
Citation Count: 7
On sectional curvatures of a Weyl manifold
(2006) Özdeğer, Abdülkadir
In this paper it is proved that if at each point of a Weyl manifold the sectional curvature is independent of the plane chosen then the Weyl manifold is locally conformal to an Einstein manifold and that the scalar curvature of the Weyl manifold is prolonged covariant constant.
Citation Count: 22
Selective liquid-liquid extraction of mercuric ions by octyl methane sulfonamide
(Marcel Dekker Inc, 2003) Bıçak, Niyazi; Sungur, Sana; Gazi, Mustafa; Tan, Nükhet
N-octyl methane sulfonamide (OMSA) has been demonstrated to be a very efficient reagent for selective extraction of Hg(II) ions from aqueous solutions. The extraction bases on rapid reaction of OMSA with Hg(II) ions yielding mono and disulfonamido mercury compounds in ordinary conditions. Solubility of OMSA and its mercury compounds in 2-ethyl hexanol provide a clear-cut phase separation in the extraction. The solution of OMSA in 2-ethyl hexanol (0.4 mol L-1) is able to extract 82.2% of mercuric-acetate (0.4 mol L-1) in non-buffered conditions. Although the process depends on the nature of accompanying anions the distribution coefficient is reasonably high (k(d) greater than or equal to 1.27) even in the presence of chloride ions. The extraction is strictly selective and the presence of Cd(II) Zn(II) Pb(II) do not bring any interference. The extraction system works in moderate concentrations. Extracted mercury in the organic phase can be recovered by back-extraction with concentrated HCl or H2SO4 solutions. After acid treatment the organic solution of OMSA becomes regenerated without losing its activity due to reasonable hydrolytic stability of the sulfonamide linkage and it can be recycled for further extractions.

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Browsing Fakülteler by Department "Fakülteler, Fen - Edebiyat Fakültesi, İstatistik ve Bilgisayar Bilimleri Bölümü"